Organic Chemistry of Explosives - primeira edição

EAN (ISBN-13): 9780470029671
ISBN (ISBN-10): 0470029676
Livro de capa dura
Ano de publicação: 2006
Editor/Editora: Wiley
414 Páginas
Peso: 0,931 kg
Língua: eng/Englisch

Livro na base de dados desde 2007-05-06T13:29:39-03:00 (Sao Paulo)
Página de detalhes modificada pela última vez em 2023-07-08T19:02:34-03:00 (Sao Paulo)
Número ISBN/EAN: 9780470029671

Número ISBN - Ortografia alternativa:
0-470-02967-6, 978-0-470-02967-1
Ortografia alternativa e termos de pesquisa relacionados:
Autor do livro: prakash, hodgson, agrawal, prak, wiley john sons
Título do livro: explosives, explosiv, organic chemistry

---

Dados da editora

Autor: Jai Prakash Agrawal; Robert Hodgson
Título: Organic Chemistry of Explosives
Editora: John Wiley & Sons
414 Páginas
Ano de publicação: 2006-11-24
Peso: 0,836 kg
Língua: Inglês
192,00 € (DE)
No longer receiving updates
168mm x 251mm x 27mm

BB; Hardcover, Softcover / Chemie/Organische Chemie; Organische Chemie; Chemie; Chemistry; Explosiv- und Treibstoffe; Explosives and Propellants; Explosivstoff; Organic Chemistry; Organische Chemie; Explosiv- und Treibstoffe; Organische Chemie

Foreword. Preface. Abbreviations. Acknowledgements. Background. 1 Synthetic Routes to Aliphatic C-Nitro Functionality. 1.1 Introduction. 1.2 Aliphatic C-nitro compounds as explosives. 1.3 Direct nitration of alkanes. 1.4 Addition of nitric acid, nitrogen oxides and related compounds to unsaturated bonds. 1.5 Halide displacement. 1.6 Oxidation and nitration of C-N bonds. 1.7 Kaplan-Shechter reaction. 1.8 Nitration of compounds containing acidic hydrogen. 1.9 Oxidative dimerization. 1.10 Addition and condensation reactions. 1.11 Derivatives of polynitroaliphatic alcohols. 1.12 Miscellaneous. 1.13 Chemical stability of polynitroaliphatic compounds. 2 Energetic Compounds 1: Polynitropolycycloalkanes. 2.1 Caged structures as energetic materials. 2.2 Cyclopropanes and spirocyclopropanes. 2.3 Cyclobutanes and their derivatives. 2.4 Cubanes. 2.5 Homocubanes. 2.6 Prismanes. 2.7 Adamantanes. 2.8 Polynitrobicycloalkanes. 3 Synthetic Routes to Nitrate Esters. 3.1 Nitrate esters as explosives. 3.2 Nitration of the parent alcohol. 3.3 Nucleophilic displacement with nitrate anion. 3.4 Nitrate esters from the ring-opening of strained oxygen heterocycles. 3.5 Nitrodesilylation. 3.6 Additions to alkenes. 3.7 Deamination. 3.8 Miscellaneous methods. 3.9 Synthetic routes to some polyols and their nitrate ester derivatives. 3.10 Energetic nitrate esters. 4 Synthetic Routes to Aromatic C-Nitro Compounds. 4.1 Introduction. 4.2 Polynitroarylenes as explosives. 4.3 Nitration. 4.4 Nitrosation-oxidation. 4.5 Nitramine rearrangement. 4.6 Reaction of diazonium salts with nitrite anion. 4.7 Oxidation of arylamines, arylhydroxylamines and other derivatives. 4.8 Nucleophilic aromatic substitution. 4.9 The chemistry of 2,4,6-trinitrotoluene (TNT). 4.10 Conjugation and thermally insensitive explosives. References. 5 Synthetic Routes to N-Nitro Functionality. 5.1 Introduction. 5.2 Nitramines, nitramides and nitrimines as explosives. 5.3 Direct nitration of amines. 5.4 Nitration of chloramines. 5.5 N-Nitration of amides and related compounds. 5.6 Nitrolysis. 5.7 Nitrative cleavage of other nitrogen bonds. 5.8 Ring-opening nitration of strained nitrogen heterocycles. 5.9 Nitrosamine oxidation. 5.10 Hydrolysis of nitramides and nitroureas. 5.11 Dehydration of nitrate salts. 5.12 Other methods. 5.13 Primary nitramines as nucleophiles. 5.14 Aromatic nitramines. 5.15 The nitrolysis of hexamine. 6 Energetic Compounds 2: Nitramines and Their Derivatives. 6.1 Cyclopropanes. 6.2 Cyclobutanes. 6.3 Azetidines - 1,3,3-trinitroazetidine (TNAZ). 6.4 Cubane-based nitramines. 6.5 Diazocines. 6.6 Bicycles 271 6.7 Caged heterocycles - isowurtzitanes. 6.8 Heterocyclic nitramines derived from Mannich reactions. 6.9 Nitroureas. 6.10 Other energetic nitramines. 6.11 Energetic groups. 7 Energetic Compounds 3: N-Heterocycles. 7.1 Introduction. 7.2 5-Membered rings - 1N - pyrroles. 7.3 5-Membered rings - 2N. 7.4 5-Membered rings - 3N. 7.5 5-Membered rings - 4N. 7.6 6-Membered rings - 1N - pyridines. 7.7 6-Membered rings - 2N. 7.8 6-Membered rings - 3N. 7.9 6-Membered rings - 4N. 7.10 Dibenzotetraazapentalenes. 8 Miscellaneous Explosive Compounds. 8.1 Organic azides. 8.2 Peroxides. 8.3 Diazophenols. 8.4 Nitrogen-rich compounds from guanidine and its derivatives. References. 9 Dinitrogen Pentoxide - An Eco-Friendly Nitrating Agent. 9.1 Introduction. 9.2 Nitrations with dinitrogen pentoxide. 9.3 The chemistry of dinitrogen pentoxide. 9.4 Preparation of dinitrogen pentoxide. 9.5 C-nitration. 9.6 N-nitration. 9.7 Nitrolysis. 9.8 O-nitration. 9.9 Ring cleavage nitration. 9.10 Selective O-nitration. 9.11 Synthesis of the high performance and eco-friendly oxidizer - ammonium dinitramide. References. Index.