2011, ISBN: 9783642148392

[ED: Buch], [PU: Springer Berlin Heidelberg], Neuware - The functionalization of surfaces on the nanoscale is one of the most fascinating and at the same time challenging topics in scienc… mais…

[ED: Buch], [PU: Springer Berlin Heidelberg], Neuware - The functionalization of surfaces on the nanoscale is one of the most fascinating and at the same time challenging topics in science. It is the key to tailoring catalysts, sensors, or devices for solar energy conversion, whose functional principle is based on the interaction of an active solid surface with another (liquid or gaseous) phase. As an example, planar transition metal complexes adsorbed on solid supports are promising candidates for novel heterogeneous catalysts. An important feature of these catalysts, compared to supported metal clusters, is the fact that the active sites, i. e. , the coordinated metal centers with their vacant axial coordination sites, are well de ned and uniform. Metalloporphyrinoids are particularly suitable in this respect because they combine a structure forming element-the rigid molecular frame, which often induces long range order-with an active site, the coordinated metal ion. Its planar coordination environment leaves two axial coordination sites available for additional ligands. If adsorbed on a surface, one of these axial sites is occupied by the underlying substrate. The resulting electronic interaction with the surface can be used to tailor the electronic structure and thereby the reactivity of the metal center. The remaining site is free for the attachment of molecules (sensor functionality) and/or operates as a reaction center (single-site catalysis). Prototype examples are omnipresent in nature, where in particular metallo-tetrapyrrols play a decisive role in important biological processes, with the most prominent examples being iron porphyrins in heme, magnesium porphyrins in chlorophyll, and cobalt corrin in vitamin B12.- Besorgungstitel - vorauss. Lieferzeit 3-5 Tage., DE, [SC: 2.70], Neuware, gewerbliches Angebot, 241x160x16 mm, 192, [GW: 494g], Banküberweisung, Offene Rechnung, Kreditkarte, PayPal, Offene Rechnung (Vorkasse vorbehalten), Internationaler Versand<

2010, ISBN: 9783642148392

Edição encadernada

[ED: Gebunden], [PU: Springer Berlin Heidelberg], Dieser Artikel ist ein Print on Demand Artikel und wird nach Ihrer Bestellung fuer Sie gedruckt. - Nominated by the University of Erlange… mais…

[ED: Gebunden], [PU: Springer Berlin Heidelberg], Dieser Artikel ist ein Print on Demand Artikel und wird nach Ihrer Bestellung fuer Sie gedruckt. - Nominated by the University of Erlangen for a Springer Theses Prize.- A fundamental contribution which has led to a new level of understanding in the field of, DE, [SC: 0.00], Neuware, gewerbliches Angebot, Hardcover, 164, [GW: 399g], 1. Auflage, Banküberweisung, PayPal, [CT: Naturwissenschaft/Mathematik / Sonstiges - Naturwissenschaften]<

2010, ISBN: 3642148395

Based on scanning tunneling microscopy investigations, this book presents several novel and fundamental contributions, which has led to a new level of understanding in the field of self-a… mais…

Based on scanning tunneling microscopy investigations, this book presents several novel and fundamental contributions, which has led to a new level of understanding in the field of self-assembly of large organic molecules. Media Buch, 164 Seiten, Media > Books, Springer, 2010<